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What is Stainless Steel?

Stainless steel is a metal alloy consisting of nickel, chromium, molybdenum, and other additives. Generally, the composition ratios of this alloy vary and depend on the target properties or use, however, a composition of at least 10.5% chromium and less than 1.2% carbon is required for it to be considered "stainless" [1][2]. As the name suggests, stainless steel is created to be more corrosion resistant to exposure compared to other materials such as carbon or alloy steels. As a result of its exposure resistance, high durability, aesthetics, and hygienic properties, stainless steel play a prominent role in a wide variety of industrial processes, and the production of consumer goods [2][3].


Alloys

Alloys are uniform metallic materials composed of at least one metal and one non-metal in its most simplest form. In order for this combination to be considered uniform and thus an alloy, it must be a solid solution, a compound, or a mixture. Alloys are preferred over other materials because of the enhanced mechanical or chemical properties associated with combining elements [7]. In addition, this combination can be accomplished with little or no reductions in the desired attributes associated with the pure metals it is comprised of; including conductivity and ductility. Such properties would mean that alloys can be used to create products with increased durability and strength, which contributes to its overall longer longevity [8].


Figure 4: Alloys are often stronger than other metals at a lighter or equal weight. Other chemical and mechanical properties are also often improved [9].

Often, alloys can be seen used for both industrial and commercial purposes as a result of it's machinability [8][9]. Examples include structural components of vehicles such as aircraft, bicycles, and automobiles. Commercial applications include kitchenware and utensils such as forks, knives, and saucepans [8].

    • Binary alloys are created when two or more metals in metal state are combined.

    • Alloys retain good tensile, compression, sheer, and flexural strength.

    • In addition to high strength, alloys usually have high conductivity and resistance.

    • Some alloys have comparable strength-to-weight ratios to ceramics while being much ductile because they do not shatter upon impact.

Figure 1: There are numerous grades of stainless steel that vary in composition, shapes, and mechanical strength [4].

Figure 2: The composition of a stainless steel sample measured by weight-percent (stainless steel UNS S31603) [5].

Figure 3: Stainless steel is used extensively used for engineering purposes such as piping [6].

Applications of Stainless Steel

As a common alloy, stainless steel sees significant usage in engineering within different industries. It can be seen used in oil and gas, water utility, medical, electrical practices and much more. Through its extensive use, multiple variants and grade of stainless steel are available based on the different environments it's intended to be used in. For example, if stainless steel were to be used in a marine environment, a chloride variant would need to be used in order to resist corrosion from salty seawater. Furthermore, the application of stainless steel is able to alleviate costs due to corrosion damage; according to the US Federal Highway Administration, it is estimated that the US spends about 276 billion dollars a year on damage caused by corrosion. If more stainless steel were used instead of other pure metals, this amount would go down with increased reliability [9].

Figure 5: The corrosion of pipes can be caused by exposure to sulfides, oxides, and hydroxides. This deformation not only results in expensive costs, but can also be harmful to human health and the environment [10].

Applications of Stainless Steel Piping Within Chemical Engineering

One major application of stainless steel within Chemical Engineering is in piping. Piping allows for the transport of masses such as fluids and gases which are common in large chemical plants and processes. For example, pipes of various lengths and diameters transport raw materials, intermediary chemicals, and products between different condensers, mixers, evaporators, etc. As a result of a wide variety of pressures, temperatures, and exposure, the material that the pipe is made of is crucial [11].

Industrial Usages

Some of the most common applications of stainless steel pipes can be found in Chemical Engineering industries [11][12]:

      • Food and Pharmaceutical Processing

      • Oil, Gas, and Energy

      • Environmental and Water Treatment Plants

      • Materials and Manufacturing

Chemical Plants and Refineries

Currently, stainless steel pipes are considered to be a mainstay of fluid systems with it's heavy usage in chemical and petrochemical plants [12]. It's chemical and mechanical properties makes stainless steel a better material than carbon steel; the thin layer of chromium oxide formed on the surface by the chromium of the alloy prevents corrosion from penetrating the surface. In addition, stainless steel is 100% recyclable making it much more environmentally friendly than alternatives - about all of stainless steel products, including piping, contains up to 60% of recycled material. The advantages of stainless steel for chemical plants and refineries are as described [12][13]:

Adaptability and Ease of Use:
        • Stainless steel equipment, tanks, and structural elements are easily to modify
        • Fluid systems using stainless steel welded pipes can be reworked while in operation
        • Rework with little risk of leakage (millibar per second or less)
Resistance to Corrosion:
        • Protected by most forms of corrosion, most common being oxidation
        • Best overall resistance to chemicals
        • Damaged oxide layer can be self-repaired; fresh exposed chromium is oxidized
Alleviates Operation Costs:
        • Higher initial purchase price
        • Lower long run costs from repairs
        • Less chance of failure and the need of repair
Food and Pharmaceutical

Stainless steel pipes sees heavy usage in food processing where cleanliness and sanitation is of the highest importance. Through fabrication, stainless steel pipes are smooth and crack free. This prevents the buildup of bacteria and microorganisms. The two most common types of stainless steel within the food industry are 304 and 316 stainless steel [12][14].

304-stainless steel
        • Excellent anti corrosion properties

        • Suitable for most food and biological products

        • Passivated surface compromised in the presence of chlorides

        • Chlorides can cause pitting

316-stainless steel:
        • Stronger resistance to chlorides compared to 304

        • Use for meat products

        • Use for products with mild salt content

Duplex-stainless steel:
        • Useful for stagnant or slow moving processes

        • Use for briny or salty foods

        • Applications where higher temperatures are required

Advantages and Disadvantages of Stainless Steel Pipes

Advantages

Disadvantages

  • Takes less preparation time before assembly compared to carbon steel [15]

    • Carbon steel needs to be coated before shipping, protective coat needs to be removed before welding and joining

  • Available as welded tubing

    • Less expensive than seamless tubing

  • Stronger than aluminium pipes

    • Easier to weld than aluminium pipes

  • High strength and durability

  • Good for high temperature environments

  • Resistant to UV exposure

  • Can be treated to prevent microbial growth

  • Heavier than aluminium pipes [15]

  • Harder to work with and more expensive compared to plastic pipes

  • Less flexible than plastic pipes

  • Vulnerable to corrosion caused by chlorides

Damage and Contamination Through Contact

The following can cause contamination if they come in contact with stainless steel [14]

      • Affixing a non-stainless metals with stainless steel

      • Contact with carbon steel can cause contamination; spot corrosion

      • Hypochlorites, such as bleach

      • Sparks from welding and grinding; contaminate rust exposed surfaces

      • Long Term contact with other metals; galvanic corrosion

What To Use To Disinfect Stainless Steel
        • Nitric Acid

        • Iodine and Ammonium solutions

Ease of Keeping Clean
        • Smooth, non-porous, robust material

        • Majority of different cleaning processes

        • Can use Sodium Hydroxide clean-in-place system

Selection Based on Requirements

Connection Types/Joining Methods

Welding

Welding is a manufacturing process where parts/components are joined together through heat. Welding stainless steel is more difficult than other materials such as carbon steel because you need to exercise more care in temperature and choice of filler material.

      • Tig welding to connect 2 pieces of stainless steel

      • Good sanitation of pieces if done correctly
Tri-Clamp
Bevel Seat
DIN
SMS
Cam and Groove
NPT Thread
Garden Hose Thread
Hose Barb
Push to Connect

Stainless Steel Pipe Sizing

Figure : Stainless steel pipe sizing chart/specifications.

Passivation

Passivation is a post fabrication treatment process where 

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