Low Density Polyethylene (LDPE)

Table of Contents

What is LDPE

Low Density Polyethylene is a branch of polyethylene with a density of 0.910–0.940 g/cm3. What fundamentally separates LDPE from its HDPE counterpart, is the structure of their polymer chain. Despite both being constituted by ethylene monomers, LDPE possesses a polymer chain with side branches. There branches are responsible for LDPE's low density as they have an irregular shapes and causes gap in-between each polymer chains. LDPE have a melting point of 105-115°C [1].


Figure 1: Polymer chain of polyethylene [2]

Image of a polymer chain of polyethylene.



Advantages and Disadvantages

LDPE Advantages

LDPE Disadvantages

  • Electrical Insulator [1]
  • Low water absorption
  • Transparent in thin film form
  • High impact strength at low temperature, good weatherability
  • Low cost
  • Vulnerable to stress cracking [1]
  • Limited usage under extreme temperature
  • High gas permeability
  • Highly flammable



LDPE Chemical Compatibilities

When not exposed to strong oxidizing agents, LDEP remains unreactive at room temperature. It is able to withstand a temperature of 80°C - 95°C under a short operation time. While the nature of LDPE being tough and flexible, it can still break under high pressure condition. Comparing to HDPE, LDPE shows lower tensile strength yet higher resilience [3].

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Table of LDPE's chemical properties [3]

ElementLDPE's corresponding resistanceChemical reaction with LDPE
AcidExcellentNone
BaseExcellentNone
EsterExcellentNone

Aldehydes

GoodLow
KetonesGoodLow
Vegetable oilGoodLow
AliphaticLimited Significant
AromaticLimited Significant
HydrocarbonsLimited Significant
Mineral oilLimited Significant
Oxidizing agentLimited Significant
Halogenated hydrocarbonsPoorViolent

LDPE Pipes Applications and Fitting

Common LDPE piping have a outer diameter ranging from 12mm to 75mm. with a maximum pressure of up to 10 bars. When compared to HDPE pipes, LDPE pipes are much smaller in size, therefore LDPE pipes are often used to transport solvents such as water in low quantities. It sees most frequently applications in: drainage, agriculture, gardening, and irrigation systems [4].

Some applicable methods of joining LDPE pipes[4]:

  • Mechanical Connectors
  • Inside Welding
  • Electro Fusing

When fitting LDPE pipes, the inner diameter of the pipe is measured for the fitting. 


Figure 2: A sizing chart of LDPE [5]

Image of an LDPE sizing chart.

LDPE Recycling

Despite both being polyethylene, LDPE must be recycled separately from its high density counterparts, giving it a recycling number of 4. Although it was not accepted for most recycling programs in the past, more communities starts to adopting the progress as LDPE is one of the most produced plastic. During recycling, processors melts down LDPE to eliminate its contaminants and then form them into thin resalable plastic sheets. 


Figure 3: Recycling symbol of LDPE [6]

Image of the LDPE recycling symbol. The symbol is the number four within a triangle constructed of three arrows.

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Faculty Advisor: Mary Robinson